Scientific Papers in SCI

The main goal of the present study was to explore photocatalytic performance of the TiO2 -CuO mixture, for solar to hydrogen conversion at pilot plant scale under two different irradiation conditions (sunny and partly cloudy), focusing on high-temperature pretreat-ment of the catalyst mixture to try to improve TiO2 doping with copper. P25-TiO2 and commercial CuO were used with different amounts of Cu (2 wt% or 7 wt% Cu) calcined at 200-400 degrees C during several hours. Catalysts were tested at pilot plant scale using solar compound parabolic collectors, with glycerol as the sacrificial agent. The photocatalyst prepared after heating at 200 degrees C for 3 h and with 7 wt% Cu, resulted in higher hydrogen production than under the other heating conditions, and results were slightly better (5 -10%) than the reference values with the untreated catalysts. Photocatalytic efficiency was slightly lower at the higher calcination temperature (400 degrees C). CO2 production and formation of formate and glycolate clearly demonstrated glycerol photoreforming. The Cu from the calcined catalyst remaining on the solid was significantly less (2.5%) than on the non -calcined catalyst (4.2%), with an important fraction of lixiviated copper and copper deposition on the reactor walls. This is a critical drawback that must be considered for large-scale applications.

This review discusses the importance of mitigating CO2 emissions by valorizing CO2 through high-pressure catalytic processes. It focuses on various key processes, including CO2 methanation, reverse water-gas shift, methane dry reforming, methanol, and dimethyl ether synthesis, emphasizing pros and cons of high-pressure operation. CO2 methanation, methanol synthesis, and dimethyl ether synthesis reactions are thermodynami-cally favored under high-pressure conditions. However, in the case of methane dry reforming and reverse water -gas shift, applying high pressure, results in decreased selectivity toward desired products and an increase in coke production, which can be detrimental to both the catalyst and the reaction system. Nevertheless, high-pressure utilization proves industrially advantageous for cost reduction when these processes are integrated with Fischer-Tropsch or methanol synthesis units. This review also compiles recent advances in heterogeneous catalysts design for high-pressure applications. By examining the impact of pressure on CO2 valorization and the state of the art, this work contributes to improving scientific understanding and optimizing these processes for sustainable CO2 management, as well as addressing challenges in high-pressure CO2 valorization that are crucial for industrial scaling-up. This includes the development of cost-effective and robust reactor materials and the development of low-cost catalysts that yield improved selectivity and long-term stability under realistic working environments.