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Artículos SCI



2017


The Oxy-CaL process: A novel CO2 capture system by integrating partial oxy-combustion with the Calcium-Looping process


Ortiz, C; Valverde, JM; Chacartegui, R; Benitez-Guerrero, M; Perejon, A; Romeo, LM
Applied Energy, 196 (2017) 1-17

ABSTRACT

This paper proposes a novel CO2 capture technology from the integration of partial oxy-combustion and the Calcium -Looping capture process based on the multicycle carbonation/calcination of limestone derived CaO. The concentration of CO2 in the carbonator reactor is increased by means of partial oxycombustion, which enhances the multicycle CaO conversion according to thermogravimetric analysis results carried out in our work, thus improving the CO2 capture efficiency. On the other hand, energy consumption for partial oxy-combustion is substantially reduced as compared to total oxy-combustion. All in all, process simulations indicate that the integration of both processes has potential advantages mainly regarding power plant flexibility whereas the overall energy penalty is not increased. Thus, the resulting energy consumption per kilogram of CO2 avoided is kept smaller than 4 MI/kg CO2, which remains below the typical values reported for total oxy-combustion and amine based CO2 capture systems whereas CO2 capture efficiency is enhanced in comparison with the Calcium -Looping process.


Junio, 2017 | DOI: 5,746

A novel, simple and rapid route to the synthesis of boron cabonitride nanosheets: combustive gaseous unfolding


Jalaly, Maisam; Jose Gotor, Francisco; Semnan, Masih; Jesus Sayagues, Maria
Scientific Reports, 7 (2017) art. 3453

ABSTRACT

The ternary compound boron carbonitride (BCN) was synthesized in the form of few-layer nanosheets through a mechanically induced self-sustaining reaction (MSR). Magnesium was used to reduce boron trioxide in the presence of melamine in a combustive manner. The process to form the nanostructured material was very rapid (less than 40 min). The prepared powder was investigated by various techniques such as X-ray diffraction (XRD), Fourier Transform infrared (FTIR), Micro-Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy (HRTEM), and electron energy loss spectroscopy (EELS). The thermal stability and the optical behavior of the BCN nanosheets were also studied by thermal analysis and UV-vis spectroscopy, respectively. The formation mechanism of the nanosheet morphology was described in detail.


Junio, 2017 | DOI: 10.1038/s41598-017-03794-7

In Situ Determination of the Water Condensation Mechanisms on Superhydrophobic and Superhydrophilic Titanium Dioxide Nanotubes


Macias-Montero, Manuel; Lopez-Santos, Carmen; Nicolas Filippin, A.; Rico, Victor J.; Espinos, Juan P.; Fraxedas, Jordi; Perez-Dieste, Virginia; Escudero, Carlos; Gonzalez-Elipe, Agustin R.; Borras, Ana
Langmuir, 33 (2017) 6449-6456

ABSTRACT

One-dimensional (1D) nanostructured surfaces based on high-density arrays of nanowires and nanotubes of photoactive titanium dioxide (TiO2) present a tunable wetting behavior from superhydrophobic to superhydrophilic states. These situations are depicted in a reversible way by simply irradiating with ultraviolet light (superhydrophobic to superhydrophilic) and storage in dark. In this article, we combine in situ environmental scanning electron microscopy (ESEM) and near ambient pressure photoemission analysis (NAPP) to understand this transition. These experiments reveal complementary information at microscopic and atomic level reflecting the surface wettability and chemical state modifications experienced by these 1D surfaces upon irradiation. We pay special attention to the role of the water condensation mechanisms and try to elucidate the relationship between apparent water contact angles of sessile drops under ambient conditions at the macroscale with the formation of droplets by water condensation at low temperature and increasing humidity on the nanotubes surfaces. Thus, for the as-grown nanotubes, we reveal a metastable and superhydrophobic Cassie state for sessile drops that tunes toward water dropwise condensation at the microscale compatible with a partial hydrophobic Wenzel state. For the UV-irradiated surfaces, a filmwise wetting behavior is observed for both condensed water and sessile droplets. NAPP analyses show a hydroxyl accumulation on the as-grown nanotubes surfaces during the exposure to water condensation conditions, whereas the water filmwise condensation on a previously hydroxyl enriched surface is proved for the superhydrophilic counterpart.


Junio, 2017 | DOI: 10.1021/acs.langmuir.7b00156

Effect of the impact energy on the chemical homogeneity of a (Ti,Ta,Nb)(C,N) solid solution obtained via a mechanically induced self-sustaining reaction


de La Obra, AG; Gotor, FJ; Chicardi, E
Journal of Alloys and Compounds, 708 (2017) 1008-1017

ABSTRACT

A titanium-tantalum-niobium carbonitride solid solution, (Ti,Ta,Nb)(C,N), was synthesised in a planetary mill via a mechanochemical process that involves a mechanically induced self-sustaining reaction (MSR) from stoichiometric Ti/Ta/Nb/C mixtures that are milled under a nitrogen atmosphere. The influence of the spinning rate of the planetary mill, which determines the impact energy of the milling process, on the ignition time (t(ig)) of the MSR process as well as the chemical homogeneity of the final product was analysed. The results indicated that the dependence of tig on the spinning rate followed a potential function with a potential factor of 4.85, implying a remarkable reduction in the milling time required to induce the self-sustaining reaction at increasing spinning rates (i.e., from 4200 min at 200 rpm to 15 min at 800 rpm). However, the chemical and structural characterisation of the obtained products at ignition without any extra milling treatment indicated that a single solid solution phase was only obtained at the lowest spinning rates (i.e., less than 300 rpm). At increasing rates, the relative amount of the intended solid solution phase continuously decreased, and new undesirable secondary phases were formed. Despite the long milling times required for the milling experiments that were performed at the slowest spinning rates, iron contamination from the milling media was negligible due to the low intensity milling regime.


Junio, 2017 | DOI: 10.1016/j.jallcom.2017.03.109

High-temperature creep of carbon nanofiber-reinforced and graphene oxide-reinforced alumina composites sintered by spark plasma sintering


Cano-Crespo, Rafael; Malmal Moshtaghioun, Bibi; Gomez-Garcia, Diego; Dominguez-Rodriguez, Arturo; Moreno, Rodrigo
Ceramisc International, 43 (2017) 7136-7141

ABSTRACT

Alumina (Al2O3) ceramic composites reinforced with either graphene oxide (GO) or carbon nanofibers (CNFs) were prepared using Spark Plasma Sintering. The effects of GO and CNFs on the microstructure and in consequence on their mechanical properties were investigated. The microstructure of the sintered materials have been characterized quantitatively prior to and after the creep experiments in order to discover the deformation mechanism. Graphene-oxide reinforced alumina composites were found to be more creep resistant than carbon nanofibers-reinforced alumina ones or monolithic alumina with the same grain size distribution. In all the cases, grain boundary sliding was identified as the deformation mechanism


Junio, 2017 | DOI: 10.1016/j.ceramint.2017.02.146

About the enhancement of chemical yield during the atmospheric plasma synthesis of ammonia in a ferroelectric packed bed reactor


Gomez-Ramirez, Ana; Montoro-Damas, Antonio M.; Cotrino, Jose; Lambert, Richard M.; Gonzalez-Elipe, Agustin R.
Plasma Processes and Polymers, 14 (2017) e1600081

ABSTRACT

Plasma reactions offer an attractive alternative route for the synthesis of a variety of valuable chemical compounds. Here we investigate the parameters that determine the efficiency of ammonia synthesis in a ferroelectric packed bed dielectric barrier discharge (DBD) reactor. The effects of varying the operating frequency, the size of the ferroelectric pellets and the inter-electrode distance have been systematically studied. Under optimised conditions nitrogen conversions in excess of 7% were achieved, higher than those previously obtained using DBD reactors. These findings are discussed with respect to variations in the electrical characteristics of the reactor under operating conditions and in the light of emission spectra obtained as a function of reactant flow rates. These encouraging results signpost future developments that could very substantially improve the efficiency of ammonia synthesis by means of DBD technology.


Junio, 2017 | DOI: 10.1002/ppap.201600081

A compact and portable optofluidic device for detection of liquid properties and label-free sensing


Lahoz, F; Martin, IR; Walo, D; Gil-Rostra, J; Yubero, F; Gonzalez-Elipe, AR
Journal of Physics D: Applied Physics, 50 (2017) 21

ABSTRACT

Optofluidic lasers have been widely investigated over the last few years mainly because they can be easily integrated in sensor devices. However, high power pulse lasers arc required as excitation sources, which, in practice, limit the portability of the system. Trying to overcome some of these limitations, in this paper we propose the combined use of a small CW laser with a Fabry-Perot optofluidic planar microcavity showing high sensitivity and versatility for detection of liquid properties and label-free sensing. Firstly, a fluorescein solution in ethanol is used to demonstrate the high performances of the FP microcavity as a temperature sensor both in the laser (high pump power above laser threshold) and in the fluorescence (low pump power) regimes. A shift in the wavelength of the resonant cavity modes is used to detect changes in the temperature and our results show that high sensitivities could be already obtained using cheap and portable CW diode lasers. In the second part of the paper, the demonstration of this portable device for label-free sensing is illustrated under low CW pumping. The wavelength positions of the optolluidic resonant modes are used to detect glucose concentrations in water solutions using a protein labelled with a fluorescent dye as the active medium.


Junio, 2017 | DOI: 10.1088/1361-6463/aa6cdd

Non-isothermal Characterization of the Precipitation Hardening of a Cu-11Ni-19Zn-1Sn Alloy


Donoso, E; Dianez, MJ; Criado, JM; Espinoza, R; Mosquera, E
Metallurgical and Materials Transactions A-Physical Metallurgy and Materials Science, 48A (2017) 3090-3095

ABSTRACT

The precipitation hardening of a Cu-11Ni-19Zn-1Sn alloy has been studied by means of Differential Scanning Calorimetry (DSC), High-Resolution Transmission Electron Microscopy (HRTEM), and hardness measurements. The calorimetric curves, in the range of temperatures analyzed, show the presence of one exothermic reaction followed by an endothermic one. The exothermic DSC peak is due to the segregation of Cu2NiZn precipitates and it is associated to a noticeable improvement of the mechanical properties of the alloy. The endothermic effect is associated to the dissolution of the Cu2NiZn precipitates into the copper matrix for restoring the starting Cu-11Ni-19Zn-1Sn homogeneous solid solution. The reaction mechanisms of these processes have been proposed from the kinetic analysis of the exothermic and endothermic DSC signals. The results obtained point out that tin plays a decisive role on the precipitation hardening of the alloy, because age hardening is not observed in the case of a Cu-Ni-Zn ternary alloy of similar composition.


Junio, 2017 | DOI: 10.1007/s11661-017-4063-4

Failure mode and effect analysis of a large scale thin-film CIGS photovoltaic module


Delgado-Sanchez, JM; Sanchez-Cortezon, E; Lopez-Lopez, C; Aninat, R; Alba, MD
Engireering failure analysis, 76 (2017) 55-60

ABSTRACT

The efficiency of thin-film CIGS based cells at the laboratory scale is now getting closer to conventional Silicon technologies. As a consequence, the long-term stability of CIGS is now one of the main challenges left to address in order to assess its potential as an alternative for photovoltaic plants. This paper reports an overview of the critical risks for the commercial viability of the CIGS thin-film technology. The key causes of the potential failures of this technology are determined through the Failure Mode Analysis and Effects (FMEA) methodology. To validate the results obtained from the FMEA, aging tests and outdoor monitoring were also carried out. Based on the results obtained, we argue that the encapsulation material is the main cause of degradation in CIGS modules. 


Junio, 2017 | DOI: 10.1016/j.engfailanal.2017.02.004

Analysis of Ni species formed on zeolites, mesoporous silica and alumina supports and their catalytic behavior in the dry reforming of methane


Drobna, Helena; Kout, Martin; Soltysek, Agnieszka; Gonzalez-Delacruz, Victor M.; Caballero, Alfonso; Capek, Libor
Reaction Kinetics Mechanisms and Catalysis, 121 (2017) 255-274

ABSTRACT

The presented investigation is focused on the analysis of Ni species formed on microporous (zeolites MFI and FAU) and mesoporous materials (Al-MCM- 41 and SBA-15) and alumina supports and their catalytic behavior in the dry reforming of methane. The paper lays emphasis on the relationship between the catalytic behavior of Ni-based catalysts and their textural/structural properties. Ni-based catalysts were prepared by wet impregnation (11 wt% of Ni) followed by calcination in air and reduction in hydrogen. The properties of Ni-based catalysts were also compared prior and after the catalytic tests. The critical role was played by the high value of the specific surface area and the high strength of the interaction between the Ni species and the support, which both determined the high dispersion and stability of metal Ni-0 particles. Ni-Al-MCM-41 and Ni-SBA-15 showed the values of the conversion of CO2 and CH4 above 90% (stable during 12 h). Slightly lower values of the conversion of CO2 and CH4 were observed over Ni-Al2O3 (also stable during 12 h). In contrast to these materials, Ni-MFI and Ni-FAU exhibited the worse metallic Ni-0 particles dispersion and very bad catalytic behavior.


Junio, 2017 | DOI: 10.1007/s11144-017-1149-3

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