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Research Projects

Flash Techniques for the Production of High-Entropy Oxides with MAGnetic Properties




01-02-2023 / 28-02-2026



Research Head: Alejandro Fernando Manchón Gordón
Organismo Financiador: Junta de Andalucía
Código: ProyExcel_00360
Grupo de Investigación: Reactividad de Sólidos

The FOMAG project focuses on the application of innovative fast sintering techniques, such as Flash Sintering (FS), Reactive Flash Sintering (RFS), and Multifaceted Flash Sintering (MPFS), for the synthesis of high-entropy oxides (HEOs) with technologically relevant magnetic properties. Despite FS being first proposed in 2010, SFR in 2018, and MPFS in 2022, interest in this process has grown significantly in various scientific fields due to its considerable scientific and technological potential

These techniques enable the fabrication of ceramic materials at significantly lower temperatures and times compared to conventional sintering methods, achieved by applying a small electric current through the sample. Furthermore, the specific experimental conditions of Flash techniques allow the production of dense and nanostructured ceramic materials, which can be challenging using conventional methods. Importantly, Flash sintering not only drastically reduces the energy consumption required for ceramic material processing but also extends its applications to new materials for technological purposes. In this context, HEOs represent an emerging class of ceramic materials with equimolar compositions containing five or more cations. The uniqueness of these systems, first proposed in 2015, lies in their extreme chemical complexity coupled with simple crystallography, where atoms arrange in a relatively straightforward crystal structure, overcoming phase separations typical in heavily doped systems. In terms of the local structure, these materials consist of an unusually high number of distinct combinations of metal-oxygen-metal bonds, inherently affecting magnetic interactions based on factors such as coordination geometry, valence, and the types of surrounding metal cations. This results in a wide range of intriguing magnetic responses.

FOMAG proposes the utilization of FS, RFS, and MPFS techniques in producing HEOs with magnetic properties, capitalizing on the inherent advantages of these techniques, particularly in achieving high density in systems where this is particularly challenging.


Development of flexible and high efficiency piezoelectric nanogenerators based on perovskite/PVDF nanocomposites




01-12-2022 / 30-11-2024



Research Head: Rocio Moriche Tirado
Organismo Financiador: Ministerio de Ciencia e Innovación
Código: TED2021-131458A-I00
Componentes: Francisco José Gotor Martínez (ICMS), María Jesús Sayagués de Vega (ICMS), Rosalía Poyato Galán (ICMS), Ana Morales Rodríguez (US), Felipe Gutiérrez Mora (US), Ángela Gallardo López (US)
Grupo de Investigación: Reactividad de Sólidos

Application of advanced disinfection processes with nanomaterials in the reduction of impact from urban pressures in the framework of circular economy




01-12-2022 / 30-11-2024



Research Head: Rosa Mosteo Abad (UNIZAR) / Mª Peña Ormad Melero (UNIZAR)
Organismo Financiador: Ministerio de Ciencia e Innovación
Código: TED2021-129267B-I00
Componentes: María Carmen Hidalgo López (ICMS), Francisca Romero Sarria (ICMS), MªPilar Goñi Cepero (UNIZAR) y Encarnación Rubio Aranda (UNIZAR)
Grupo de Investigación: Fotocatálisis Heterogénea: Aplicaciones

Water is one of the natural resources that, due to its limited and variable nature, both in quantity and quality, should be protected with special intensity, in line with the Environmental Objectives that support the ecological transition: sustainable use and protection of water and marine resources, circular economy, pollution prevention and control, and protection and restoration of biodiversity and ecosystems. Studies realized in collaboration with the Confederación Hidrográfica del Ebro, the urban point sources are the pressures that in most cases are the cause of non-compliance
with the environmental quality objectives established by the DMA. This non-compliance are mainly related to microbiological contamination in the receiving waters of these discharges.
Generally, as there is no legal requirement, wastewater treatment facilities do not include disinfection processes that reduce the microbiological load of effluents and, consequently, these agents are incorporated into natural waters, limiting the usemade of them, especially in supplying populations and recreational use (bathing and others). Likewise, such contamination in wastewater limits the possibility of its subsequent reuse, reducing the capacity to increase the availability of water resources. It is important to remark that, water reuse for agricultural irrigation can also contribute to circular economy by recovering nutrients from the reclaimed water and applying them to crops, by means of fertigation techniques. Thus, water reuse could potentially reduce the need for supplemental applications of mineral fertilizer.
Therefore, it is necessary to intensify the wastewater treatment efficiency by non-conventional processes that improve the treated water quality with the final objective of allowing a safe reuse of effluents, taking into account the regulation (EU) 2020/741. On the other hand, the control of more microbiological parameters is essential for a correct analysis of the technologies application. Aware of this need, the AySA group has been developing research projects for many years focus on the research about conventional and non-conventional processes, based on photocatalytic processes, applied for disinfection waters and about the microbiological control in urban wastewater treatment plants. The main objective of this project is to select the best technology for disinfection of treated urban wastewater for full-scale application by the improvement of previously studied advanced oxidation processes in the disinfection of these type of waters. Furthermore, the microbiological control, not only by bacterial indicators conventionally used but also protozoa and endosymbiotic bacteria that are inside amoebae, is consider very relevant in this project since to our knowledge, there are no studies investigating such a wide range of potentially pathogenic micro-organisms. This realistic approach is expected to minimise the impact on the receiving waters and increase the possibility of reuse, reducing the the health and environmental risk.


Design and selection of novel materials for the fabrication of high performance reversible solid oxide fuel cells




01-12-2022 / 30-11-2024



Research Head: Francisco José García García (US) / Juan Gabriel Lozano Suárez (US)
Organismo Financiador: Ministerio de Ciencia e Innovación
Código: TED2021-132057B-I00
Componentes: Francisco José Gotor Martínez (ICMS), María Jesús Sayagués de Vega (ICMS), Yadir Torres Hernández (US), Isabel Montealegre Meléndez (US), Cristina María Arévalo Mora (US), Ana María Beltrán Custodio (US), Eva María Pérez Soriano (US), Paloma Trueba Muñoz (US)
Grupo de Investigación: Reactividad de Sólidos

Development of intermittent plasmas ignited by renewable electricity for the CO2 splitting and revalorization processes [RENOVACO2]




01-12-2022 / 30-11-2024



Research Head: Ana María Gómez Ramírez / Manuel Oliva Ramírez
Organismo Financiador: Ministerio de Ciencia e Innovación "Transición Ecológica y Transición Digital"
Código: TED2021-130124A-I00
Componentes: Rafael Álvarez Molina, José Cotrino Bautista, María del Carmen García Martínez (US), Alberto Palmero Acebedo, Agustín R. González-Elipe
Grupo de Investigación: Nanotecnología en Superficies y Plasma

CO2 emissions currently represent the 77% of the total greenhouse gas emissions of anthropogenic origin. It provokes a gradual increase in global warming of our planet with catastrophic environmental consequences. There is no doubt about the need to promote a transition toward an economy avoiding the intensive use of fossil fuels, i.e., using the electricity generated from renewable sources as primary source of energy, and favoring alternative and more sustainable chemical processes. The project "Development of intermittent plasmas ignited by renewable electricity for the CO2 splitting and revalorization processes", RENOVACO2, aims at developing atmospheric plasma technologies that use electricity as a direct energy vector to induce chemical processes that are currently carried out through catalytic techniques (i.e., at high pressures and temperatures, using harmful and non-recyclable catalysts). RENOVACO2 is a multidisciplinary project that pursuits the development of novel physical processes for the elimination and revalorization of CO2, especially designed and optimized for their activation by means of renovably energy sources. The proposed technology consist of using atmospheric pressure plasmas to induce chemical reactions in non-equilibrium conditions at atmospheric pressure and in a distributed way.


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