Artículos SCI
2020
2020
Materiales Ópticos Multifuncionales
Finite Size Effects on Light Propagation throughout Random Media: Relation between Optical Properties and Scattering Event Statistics
Miranda-Munoz, JM; Esteso, V; Jimenez-Solano, A; Lozano, G; Miguez, HAdvanced Optical Materials, 8 (2020) 1901196
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This work introduces a thorough analysis of light transport in thin optically disordered media. The diffusive properties of a turbid material are generally dictated by the transport mean free path, lt. For depths larger than this characteristic length, light propagation can be considered fully randomized. There is however a range of thicknesses for which light becomes only partly randomized, as it only undergoes a single or very few scattering events. The effects of such finitude are experimentally and theoretically studied on the optical properties of the material, such as the angular distribution of scattered light. Simulations provide insight into the phenomena that occur within the optically disordered slab, like the number of scattering events that photons undergo during propagation throughout the material, as a function of the built‐in wavelength dependent scattering mean free path, lsc. This approach provides fundamental information about photon transport in finite optically random media, which can be put into practice to design diffusers with specific requirements in terms of the spectral and angular properties of the scattered light.
Enero, 2020 | DOI: 10.1002/adom.201901196
Materiales Avanzados
New waste-based clinkers for the preparation of low-energy cements. A step forward toward circular economy
Martinez-Martinez, S; Perez-Villarejo, L; Eliche-Quesada, D; Sanchez-Soto, PJ; Christogerou, A; Kanellopoulou, DG; Angelopoulos, GNInternational Journal of Applied Ceramic Technology, 17 (2020) 12-21
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This paper describes the use of industrial wastes arising from different production processes of the ceramic and marble industries as raw materials for the design and formulation of new cement clinkers with a high content of dicalcium silicate (Belite). The aim was to reintroduce these wastes in the industrial sector and take advantage of them for a greater environmental benefit, as indicated by the principles of the circular economy. Formulations containing 2.5, 5 and 10 wt% of chamotte and marble sludge, respectively, and a waste-free formulation have been designed to obtain clinkers with a content of dicalcium silicate higher than 60 wt%. The different blends have been studied up to a maximum temperature of 1390 degrees C by Thermal Analysis. Other techniques such as XRD, XRF, Modified Bogue Equation, Quality Indexes (LSF, AM, SM) and Optical Microscopy have been used for the study and characterization of industrial wastes, the raw materials and the high belite-type cement dosages. The results indicate that this type of cements can be designed using different types of wastes and in this way reduce the environmental impacts caused by the extraction of raw materials and the deposition of the wastes in landfills, improving the circular economy of the construction industry.
Enero, 2020 | DOI: 10.1111/ijac.13390
Reactividad de Sólidos
Obituary: Prof. José Manuel Criado
Perez-Maqueda, LA; Real, C; Gotor, FJ; Alcala, MD; Malek, J; Koga, NJournal of Thermal Analysis and Calorimetry, (2020)
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Reactividad de Sólidos
Influence of DSC thermal lag on evaluation of crystallization kinetics
Svoboda, R; Maqueda, LP; Podzemna, V; Perejon, A; Svoboda, OJournal of Non-Crystalline Solids, 528 (2020) 119738
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Influence of added thermal resistance on crystallization kinetics, as measured by differential scanning calorimetry (DSC), of the Se70Te30 glass was studied. The increase of thermal resistance was achieved by adding polytetrafluorethylene discs of different thicknesses (up to 0.5 mm) in-between the DSC platform and the pan with sample. Increase of the thermal resistance led to an apparent decrease (by more than 30%) in the crystallization enthalpy. Significant change of model-free kinetics occurred: apparent activation energy E of the crystallization process decreased (by more than 20%) due to the DSC data being progressively shifted to higher temperatures with increasing heating rate. The model-based kinetics was changed only slightly; the DSC peaks retained their asymmetry and the choice of the appropriate model was not influenced by the added thermal resistance. The temperature shift caused by added thermal lag was modeled for the low-to-moderate heating rates.
Enero, 2020 | DOI: 10.1016/j.jnoncrysol.2019.119738
Materiales Nanoestructurados y Microestructura
Low gas consumption fabrication of He-3 solid targets for nuclear reactions
Fernandez, A; Hufschmidt, D; Colaux, JL; Valiente-Dobon, JJ; Godinho, V; de Haro, MCJ; Feria, D; Gadea, A; Lucas, SMaterials & Design, 186 (2020) 108337
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![](https://icms.us-csic.es/sites/icms.us-csic.es/files/1-s2_257.png)
Nanoporous solids that stabilize trapped gas nanobubbles open new possibilities to fabricate solid targets for nuclear reactions. A methodology is described based on the magnetron sputtering (MS) technique operated under quasistatic flux conditions to produce such nanocomposites films with He-3 contents of up to 16 at.% in an amorphous-silicon matrix. In addition to the characteristic low pressure (3-6 Pa) needed for the gas discharge, the method ensures almost complete reduction of the process gas flow during film fabrication. The method could produce similar materials to those obtained under classical dynamic flux conditions for MS. The drastic reduction (>99.5%) of the gas consumption is fundamental for the fabrication of targets with scarce and expensive gases. Si:He-3 and W:He-3 targets are presented together with their microstructural (scanning and transmission electron microscopy, SEM and TEM respectively) and compositional (Ion Beam Analysis, IBA) characterization. The He-3 content achieved was over 1 x 10(18) at/cm(2) for film thicknesses between 1.5 and 3 mu m for both Si and W matrices. First experiments to probe the stability of the targets for nuclear reaction studies in inverse kinematics configurations are presented.
Enero, 2020 | DOI: 10.1016/j.matdes.2019.108337
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