Artículos SCI
2008
2008
Materiales Ópticos Multifuncionales
Comment on "Observation of higher-order diffraction features in self-assembled photonic crystals"
Dorado, LA; Depine, RA; Miguez, HPhysical Review A, 78 (2008) 037801
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The purpose of this Comment is to show that we find that the conclusions presented in a paper by Nair and Vijaya [Phys. Rev. A 76, 053805 (2007)], concerning the perfect periodic ordering of self-assembled photonic crystals, are not supported and contradict previous studies of this matter.
Septiembre, 2008 | DOI: 10.1103/PhysRevA.78.037801
Materiales de Diseño para la Energía y Medioambiente
High-temperature mechanical properties of porous NaMgF3 derived from directionally solidified NaMgF3-NaF eutectics
Ramirez-Rico, J; de Arellano-Lopez, AR; Martinez-Fernandez, J; Larrea, A; Orera, VMJournal of The European Ceramic Society, 28 (2008) 2451-2457
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Porous NaMgF3 ceramics have been fabricated by leaching a NaF-NaMgF3 eutectic in distilled water, producing NaMgF3 with 53% of connected porosity. The eutectic was fabricated using the Bridgman technique at growth rates of 8, 10 and 15 mm/h. The microstructure and composition of the resulting material has been studied by means of X-ray diffraction and SEM. Compression mechanical tests have been performed at different temperatures up to 750 degrees C, both in constant strain rate and constant stress loading. The microstructure consists of plate-like grains with cylindrical pores in approximately hexagonal packing. Pores are perpendicular in adjacent grains. The compressive strength is found to be rather independent of growth rate, in the range studied. Small differences can be explained using a minimum solid area (MSA) model and differences in the microstructure. In creep experiments, no steady-state regime was observed. Instead, the strain exhibited a series of accelerations that could be associated with damage propagation.
Septiembre, 2008 | DOI: 10.1016/j.jeurceramsoc.2008.04.002
Materiales Nanoestructurados y Microestructura - Tribología y Protección de Superficies
Influence of particle size on electrochemical and gas-phase hydrogen storage in nanocrystalline Mg
Friedrichs, O; Kolodziejczyk, L; Sanchez-Lopez, JC; Fernandez, A; Lyubenova, L; Zander, D; Koster, U; Aguey-Zinsou, KF; Klassen, T; Bormann, RJournal of Alloys and Compounds, 463 (2008) 539-545
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Nanocrystalline Mg powders of different particle size were obtained by inert gas evaporation and studied during electrochemical and gas-phase hydrogen cycling processes. The samples were compared to dehydrided samples obtained by mechanical milling of MgH2 with and without 2 mol% Nb2O5 as catalyst. The hydrogen overpotential of the pure Mg, which is a measure of the hydrogen evolution at the electrode surface, was observed to be reduced with smaller particle sizes reaching values comparable to samples with Nb2O5 additive. On the other hand gas-phase charging experiments showed the capacity loss with smaller particle sizes due to oxidation effects. These oxidation effects are different depending on the synthesis method used and showed a major influence on the hydrogen sorption kinetics.
Septiembre, 2008 | DOI: 10.1016/j.jallcom.2007.09.085
Materiales Coloidales - Materiales Ópticos Multifuncionales
Photoconducting Bragg Mirrors based on TiO2 Nanoparticle Multilayers
Calvo, ME; Colodrero, S; Rojas, TC; Anta, JA; Ocana, M; Miguez, HAdvanced Functional Materials, 18 (2008) 2708-2715
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A synthetic route to building photoconducting films of TiO2 nanoparticles that display bright structural color is presented. The color arises as a result of the periodic modulation of the refractive index, which is achieved by controlling the degree of porosity of each alternate layer through the particle size distribution of the precursor suspensions. The suspensions are cast in the shape of a film by spin-coating, which allows tailoring of the lattice parameter of the periodic multilayer, thus tuning the Bragg peak spectral position (i.e., its color) over the entire visible region. Photoelectrochemical measurements show that the Bragg mirrors are conductive and distort the photocurrent response as a result of the interplay between photon and electron transport.
Septiembre, 2008 | DOI: 10.1002/adfm.200800039
Fotocatálisis Heterogénea: Aplicaciones - Materiales y Procesos Catalíticos de Interés Ambiental y Energético
Highly photoactive ZnO by amine capping-assisted hydrothermal treatment
Colon, G; Hidalgo, MC; Navio, JA; Melian, EP; Diaz, OG; Rodriguez, JMDApplied Catalysis B-Environmental, 83 (2020) 30-38
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ZnO nanoparticles have been prepared by amine template assisted sol-gel precipitation and further hydrothermal treatment. We have investigated the effect of different pH values achieved by means of triethylamine (TEA) addition in the final surface and structural properties. Two sets of samples were obtained after thermal treatment, one with no hydrothermal pre-treatment and a second hydrothermally pre-treated. Surprisingly the precipitate obtained after the amine addition also exhibits good photocatalytic properties. It has been stated that calcination treatment leads in both sets of samples to a significant improvement in the photocatalytic properties of the studied systems. Therefore, interesting comparison has been performed between hydrothermal pre-treated and direct thermal treated samples. Surface and morphological features notably differ from ZnO prepared using different synthetic route. Wide Surface and structural characterization of the samples have been carried out, and correlations with precipitation pH are pointed out from this characterization. In all cases. the amine templated ZnO obtained exhibit high conversion values for phenol photo-oxidation reaction. Further calcination treatment in all of the studied samples clearly leads to photocatalytic conversions higher than that exhibited by TiO2 Degussa P25. This fact is even more significant if we consider that hydrothermally and calcined ZnO exhibit almost null surface area values. leading to a startling intrinsic photoactivity. The structural excellence (crystallinity, lack of defects, crystallite size, etc.) of such systems is clearly responsible for their high photoactivity values.
Septiembre, 2008 | DOI: 10.1016/j.apcatb.2008.01.033
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