Scientific Papers in SCI
2024
2024
Materiales de Diseño para la Energía y Medioambiente
Optimising anode supported BaZr1-xYxO3-δ electrolytes for solid oxide fuel cells: Microstructure, phase evolution and residual stresses analysis
Fernández Muñoz, S; Chacartegui, R; Alba, MD; Ramírez Rico, JJournal of Power Sources, 596 (2024) 234070
Yttrium-doped BaZrO3 is a promising electrolyte for intermediate-temperature protonic ceramic fuel cells. In the anode-supported configuration, a slurry containing the electrolyte is deposited on the surface of a calcined porous anode and sintered. Differences in sintering behaviour and thermal expansion coefficients for the anode and electrolyte result in elastic residual stresses that can impact the long-term stability of the cell during cyclic operation. Half-cells using BaZr0.8Y0.2O3-δ as the electrolyte were fabricated using the solid-state reaction sintering method under various sintering conditions. Comprehensive microstructure and residual stress analyses as a function of processing parameters were performed using two-dimensional X-ray diffraction, Rietveld refinement, and scanning electron microscopy, before and after the half-cells were reduced under hydrogen, giving a complete picture of phase, microstructure, and stress evolution under thermal and reduction cycles like the actual operation of the cell. Our results reveal that a temperature of 1400 °C and shorter soaking times might be advantageous for obtaining phase-pure and thin yttrium-doped BaZrO3 electrolytes with improved microstructure and the presence of compressive residual stress. These findings offer valuable insights into optimising the fabrication process of BaZrO3-based electrolytes, leading to enhanced performance and long-term stability of anode-supported protonic ceramic fuel cells operating at intermediate temperatures.
March, 2024 | DOI: 10.1016/j.jpowsour.2024.234070
Química de Superficies y Catálisis
Highly Effective Non-Noble MnO2 Catalysts for 5-Hydroxymethylfurfural Oxidation to 2,5-Furandicarboxylic Acid
Alvarez-Hernández, D; Megías-Sayago, C; Penkova, A; Centeno, MA; Ivanova, SChemsuschem, 17 (2024) e202400115
Noble metal-free catalyst or catalytic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid are proposed in this study as a proposal to solve one of the great disadvantages of this reaction of using preferably noble metal-based catalysts. The catalytic activity of six MnO2 crystal structures is studied as alternative. The obtained results showed a strong connection between catalytic activity the type of MnO2 structure organization and redox behavior. Among all tested catalysts, epsilon-MnO2 showed the best performance with an excellent yield of 74 % of 2,5-furandicarboxylic acid at full -hydroxymethylfurfural conversion.
March, 2024 | DOI: 10.1002/cssc.202400115
Materiales Semiconductores para la Sostenibilidad
Synergetic Near- and Far-Field Plasmonic Effects for Optimal All-Perovskite Tandem Solar Cells with Maximized Infrared Absorption
Bueno, J; Carretero Palacios, S; Anaya, MJournal of Physical Chemistry Letters, 15(9) (2024) 2632-2638
The efficiency and reliability of perovskite solar cells have rapidly increased in conjunction with the proposition of advanced single-junction and multi-junction designs that allow light harvesting to be maximized. However, Sn-based compositions required for optimized all-perovskite tandem devices have reduced absorption coefficients, as opposed to pure Pb perovskites. To overcome this, we investigate near- and far-field plasmonic effects to locally enhance the light absorption of infrared photons. Through optimization of the metal type, particle size, and volume concentration, we maximize effective light harvesting while minimizing parasitic absorption in all-perovskite tandem devices. Interestingly, incorporating 240 nm silver particles into the Pb-Sn perovskite layer with a volume concentration of 3.1% indicates an absolute power conversion efficiency enhancement of 2% in the tandem system. We present a promising avenue for experimentalists to realize ultrathin all-perovskite tandem devices with optimized charge carrier collection, diminishing the weight and the use of Pb.
February, 2024 | DOI: 10.1021/acs.jpclett.4c00194
Materiales para Bioingeniería y Regeneración Tisular
New Nano-Crystalline Hydroxyapatite-Polycarboxy/Sulfo Betaine Hybrid Materials: Synthesis and Characterization
Díaz-Cuenca, A; Sezanova, K; Gergulova, R; Rabadjieva, D; Ruseva, KMolecules, 29(5) (2024) 930
Hybrid materials based on calcium phosphates and synthetic polymers can potentially be used for caries protection due to their similarity to hard tissues in terms of composition, structure and a number of properties. This study is focused on the biomimetic synthesis of hybrid materials consisting of hydroxiapatite and the zwitterionic polymers polysulfobetaine (PSB) and polycarboxybetaine (PCB) using controlled media conditions with a constant pH of 8.0–8.2 and Ca/P = 1.67. The results show that pH control is a dominant factor in the crystal phase formation, so nano-crystalline hydroxyapatite with a Ca/P ratio of 1.63–1.71 was observed as the mineral phase in all the materials prepared. The final polymer content measured for the synthesized hybrid materials was 48–52%. The polymer type affects the final microstructure, and the mineral particle size is thinner and smaller in the synthesis performed using PCB than using PSB. The final intermolecular interaction of the nano-crystallized hydroxyapatite was demonstrated to be stronger with PCB than with PSB as shown by our IR and Raman spectroscopy analyses. The higher remineralization potential of the PCB-containing synthesized material was demonstrated by in vitro testing using artificial saliva.
February, 2024 | DOI: 10.3390/molecules29050930
Química de Superficies y Catálisis
Renewable Carbonaceous Materials from Biomass in Catalytic Processes: A Review
Villora-Picó, JJ; González-Arias, J; Baena-Moreno, FM; Reina, TRMaterials, 17 (2024) 565
This review paper delves into the diverse ways in which carbonaceous resources, sourced from renewable and sustainable origins, can be used in catalytic processes. Renewable carbonaceous materials that come from biomass-derived and waste feedstocks are key to developing more sustainable processes by replacing traditional carbon-based materials. By examining the potential of these renewable carbonaceous materials, this review aims to shed light on their significance in fostering environmentally conscious and sustainable practices within the realm of catalysis. The more important applications identified are biofuel production, tar removal, chemical production, photocatalytic systems, microbial fuel cell electrodes, and oxidation applications. Regarding biofuel production, biochar-supported catalysts have proved to be able to achieve biodiesel production with yields exceeding 70%. Furthermore, hydrochars and activated carbons derived from diverse biomass sources have demonstrated significant tar removal efficiency. For instance, rice husk char exhibited an increased BET surface area from 2.2 m2/g to 141 m2/g after pyrolysis at 600 °C, showcasing its effectiveness in adsorbing phenol and light aromatic hydrocarbons. Concerning chemical production and the oxidation of alcohols, the influence of biochar quantity and pre-calcination temperature on catalytic performance has been proven, achieving selectivity toward benzaldehyde exceeding 70%.
February, 2024 | DOI: 10.3390/ma17030565
Nanotecnología en Superficies y Plasma
Growth dynamics of nanocolumnar thin films deposited by magnetron sputtering at oblique angles
Alvarez, R; Garcia-Valenzuela, A; Regodon, G; Ferrer, FJ; Rico, V; Garcia-Martin, JM; Gonzalez-Elipe, AR; Palmero, ANanotechnology, 35 (2024) 095705
The morphology of numerous nanocolumnar thin films deposited by the magnetron sputtering technique at oblique geometries and at relatively low temperatures has been analyzed for materials as different as Au, Pt, Ti, Cr, TiO2, Al, HfN, Mo, V, WO3 and W. Despite similar deposition conditions, two characteristic nanostructures have been identified depending on the material: a first one defined by highly tilted and symmetric nanocolumnar structures with a relatively high film density, and a second one characterized by rather vertical and asymmetric nanocolumns, with a much lower film density. With the help of a model, the two characteristic nanostructures have been linked to different growth dynamics and, specifically, to different surface relaxation mechanisms upon the incorporation of gaseous species with kinetic energies above the surface binding energy. Moreover, in the case of Ti, a smooth structural transition between the two types of growths has been found when varying the value of the power used to maintain the plasma discharge. Based on these results, the existence of different surface relaxation mechanisms is proposed, which quantitatively explains numerous experimental results under the same conceptual framework.
February, 2024 | DOI: 10.1088/1361-6528/ad113d
Materiales Ópticos Multifuncionales - Materiales Semiconductores para la Sostenibilidad
Casimir-Lifshitz Optical Resonators: A New Platform for Exploring Physics at the Nanoscale
Esteso, V; Frustaglia, D; Carretero-Palacios, S; Míguez, HAdvanced Physics Research, 3 (2024) 2300065.
The Casimir-Lifshitz force, FC − L, has become a subject of great interest to both theoretical and applied physics communities due to its fundamental properties and potential technological implications in emerging nano-scale devices. Recent cutting-edge experiments have demonstrated the potential of quantum trapping at the nano-scale assisted by FC − L in metallic planar plates immersed in fluids through appropriate stratification of the inner dielectric media, opening up new avenues for exploring physics at the nano-scale. This review article provides an overview of the latest results in Casimir-Lifshitz based-optical resonator schemes and their potential applications in fields such as microfluidic devices, bio-nano and micro electromechanical systems (NEMS and MEMS), strong coupling, polaritonic chemistry, photo-chemistry, sensing, and metrology. The use of these optical resonators provides a versatile platform for fundamental studies and technological applications at the nano-scale, with the potential to revolutionize various fields and create new opportunities for research.
February, 2024 | DOI: 10.1002/apxr.202300065
Materiales Ópticos Multifuncionales
Strong Light-Matter Coupling in Lead Halide Perovskite Quantum Dot Solids
Bujalance, C; Caliò, Dirin, DN; Tiede, DO; Gaisteo-López, JF; Feist, J; García-Vidal, FJ; Kovalenko, MV; Míguez, HACS Nano, 18(6) (2024) 4922-4931
Strong coupling between lead halide perovskite materials and optical resonators enables both polaritonic control of the photophysical properties of these emerging semiconductors and the observation of fundamental physical phenomena. However, the difficulty in achieving optical-quality perovskite quantum dot (PQD) films showing well-defined excitonic transitions has prevented the study of strong light-matter coupling in these materials, central to the field of optoelectronics. Herein we demonstrate the formation at room temperature of multiple cavity exciton-polaritons in metallic resonators embedding highly transparent Cesium Lead Bromide quantum dot (CsPbBr3-QD) solids, revealed by a significant reconfiguration of the absorption and emission properties of the system. Our results indicate that the effects of biexciton interaction or large polaron formation, frequently invoked to explain the properties of PQDs, are seemingly absent or compensated by other more conspicuous effects in the CsPbBr3-QD optical cavity. We observe that strong coupling enables a significant reduction of the photoemission line width, as well as the ultrafast modulation of the optical absorption, controllable by means of the excitation fluence. We find that the interplay of the polariton states with the large dark state reservoir plays a decisive role in determining the dynamics of the emission and transient absorption properties of the hybridized light-quantum dot solid system. Our results should serve as the basis for future investigations of PQD solids as polaritonic materials.
February, 2024 | DOI: 10.1021/acsnano.3c10358
Fotocatálisis Heterogénea: Aplicaciones
Insights into the physicochemical properties of Sugar Scum as a sustainable biosorbent derived from sugar refinery waste for efficient cationic dye removal
F. Atmani, M.M. Kaci, N. Yeddou-Mezenner, A. Soukeur, I. Akkari, J.A. NavíoBiomass Conversion and Biorefinery, 14 (2024) 4843-4857
The objective of this study was to determine the ability of sugar scum (SS), an industrial waste, as a novel biosorbent for the removal of Basic Blue 41 (BB 41) from aqueous solutions. The biosorbent was characterized by SEM/EDS, BET, FTIR, and pHpzc measurements, respectively. To reach a maximum adsorption capacity of 26.45 mg.g–1, impacting operational factors such as pH, biosorbent dose, contact duration, starting dye concentration, and temperature were adjusted, when the removal efficiency reached 84% during 60 min at pH 10, 1.5 g.L–1 of biosorbent and Co = 10 mg.L–1. The experimental data were modeled by various isotherm models, whereas the best fit was found for Freundlich with a high correlation coefficient (R2 = 0.991). Other kinetic models including pseudo-first, pseudo-second order, and intra-particle diffusion models were tested to fit the kinetic data. The biosorption of BB 41 onto SS was spontaneous (∆G° < 0) and exothermic (∆H° < 0), while the biosoprtion mechanism of BB41 over SS was proposed with repeated reuse showing that SS could be regenerated after four successive runs. Furthermore, this study revealed that sugar scum is an underutilized bioresource in Algeria, with the potential to provide low-cost environmental removal of additional contaminants in the wastewater treatment domain.
February, 2024 | DOI: 10.1007/s13399-022-02646-3
Nanotecnología en Superficies y Plasma
Harnessing a Vibroacoustic Mode for Enabling Smart Functions on Surface Acoustic Wave Devices - Application to Icing Monitoring and Deicing
Karimzadeh, A; Weissker, U; del Moral, J; Winkler, A; Borrás, A; González-Elipe, AR; Jacob, SAdvanced Materials Technologies, (2024) 2301749
Microacoustic wave devices are essential components in the radio frequency (RF) electronics and microelectromechanical systems (MEMS) industry with increasing impact in various sensing and actuation applications. Reliable and smart operation of acoustic wave devices at low costs will cause a crucial advancement. Herein, this study presents the enablement of temperature and mechanical sensing capabilities in a Rayleigh-mode standing surface acoustic wave (sSAW) chip device by harnessing an acoustic shear-thickness dominant wave (SD) using the same set of electrodes. Most importantly, this mode is excited by switching the polarity of the sSAW transducer electrodes by simple electronics, allowing for direct and inexpensive compatibility with an existing setup. The method in the emergent topic of surface de-icing is validated by continuously monitoring temperature and liquid–solid water phase changes using the SD mode, and on-demand Rayleigh-wave deicing with a negligible energy cost. The flexibility for adapting the system to different scenarios, and loads and the potential for scalability opens the path to impact in lab-on-a-chip, internet of things (IoT) technology, and sectors requiring autonomous acoustic wave actuators.
February, 2024 | DOI: 10.1002/admt.202301749
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