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Scientific Papers in SCI



2023


Química de Superficies y Catálisis

Enroute to the Carbon-Neutrality Goals via the Targeted Development of Ammonia as a Potential Nitrogen-Based Energy Carrier

Nawaz, MA; Blay-Roger, R; Saif, M; Meng, FH; González-Arias, J; Miao, BJ; Bobadilla, LF; Ramírez-Reina, T; Odriozola, J.A.
ACS Catalysis, 13 (2023) 14415-14453

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The reliance of a future carbon-free horizon is strongly aligned with the long-term energy storage avenues which are completely derived from renewable energy resources. Ammonia with its high energy content and density can perform as a decent candidate for buffering the short-term storage options. However, the current NH3 production majorly feeding the current huge desire for ammonia is dominated by the conventional nonrenewable Haber–Bosch (H–B) process route, thus continuously damaging the target of carbon neutrality goals. High-purity hydrogen (H2) gas is an essential precursor for the H–B process; however, it is a significant energy consumer (about 2% of the global energy supply) and contributes over 420 million tons of CO2/annum. Therefore, the research on the renewable synthesis of nitrogen-based energy carriers (such as ammonia) from the direct electrochemical, photocatalytic, or plasma catalytic processes; its conversion; and utilization to the potential derivatives has been a hot topic in the past few decades. A prospective analysis of the highly appealing processes has been summarized in this study, which could facilitate the adaption of renewable alternatives as an effective approach for zero carbon emission, paving the excellent pathways along the road to the development of nitrogen-based energy technologies, especially the targeted development of ammonia. Further, this Review covers the current and future impacts of the H–B process, the development of aspiring ammonia synthesis routes (via electro, photo, bio, chemical loop, or plasma catalysis), and its conversion and utilization to the renewable derivatives in terms of fabrication of model catalysts, advanced characterization technology, and efficient device design.


October, 2023 | DOI: 10.1021/acscatal.3c02410

Materiales de Diseño para la Energía y Medioambiente

Mechanical treatments on design powder ceramic materials: Insight into the textural and structural changes

Osuna, FJ; Fernández, M; Pavón, E; Sánchez, RMT; Alba, MD
Advanced Powder Technology, 34 (2023) 104189

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Mechanical treatment of porous ceramics, such as porous clay minerals, is a crucial step in ceramic processing. Among clay minerals, design swelling brittle micas have shown exceptional properties for further applications, although they exhibit low surface area and porosity. But, their mechanical activation could improve their textural properties and deserves to be investigated. Thus, the aim of this work was to evaluate the effects of gradual grinding in their surface and framework. At short grinding times, the surface area increases and mesoporous and microporous are generated. Long grinding time provokes particle agglomeration with the consequent change in their colloidal stability. At bulk level, framework defects are observed in both tetrahedral and octahedral sheets and increase with the total layer charge.


October, 2023 | DOI: 10.1016/j.apt.2023.104189

Nanotecnología en Superficies y Plasma

Cobalt Stabilization through Mesopore Confinement on TiO2 Support for Fischer-Tropsch Reaction

Platero, F; Todorova, S; Aoudjera, L; Michelin, L; Lebeau, B; Blin, JL; Holgado, JP; Caballero, A; Colón, G
ACS Applied Energy Materials, 6 (2023) 9475-9486

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Cobalt supported on mesostructured TiO2 catalysts has been prepared by a wet-impregnation method. The Co/TiO2 catalytic system showed better catalytic performance after support calcination at 380 °C. Co nanoparticles appeared well distributed along the mesopore channels of TiO2. After reduction pretreatment and reaction, a drastic structural change leads to mesopore structure collapse and the dispersion of the Co nanoparticles on the external surface. Along this complex process, Co species first form discrete nanoparticles inside the pore and then diffuse out as the pore collapses. Through this confinement, a strong metal–support interaction effect is hindered, and highly stable metal active sites lead to better performance for Fischer–Tropsch synthesis reaction toward C5+ products.


September, 2023 | DOI: 10.1021/acsaem.3c01432

Nanotecnología en Superficies y Plasma

Germination and First Stages of Growth in Drought, Salinity, and Cold Stress Conditions of Plasma-Treated Barley Seeds

Perea-Brenes, A; Garcia, JL; Cantos, M; Cotrino, J; Gonzalez-Elipe, AR; Gomez-Ramirez, A; López-Santos, C
ACS Agricultural Science & Technology, 3 (2023) 760-770

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Numerous works have demonstrated that cold plasma treatments constitute an effective procedure to accelerate seed germination under nonstress conditions. Evidence also exists about a positive effect of plasmas for germination under environmental stress conditions. For barley seeds, this work studies the influence of cold plasma treatments on the germination rate and initial stages of plant growth in common stress environments, such as drought, salinity, and low-temperature conditions. As a general result, it has been found that the germination rate was higher for plasma-treated than for untreated seeds. Plasma also induced favorable changes in plant and radicle dimensions, which depended on the environment. The obtained results demonstrate that plasma affects the biochemical metabolic chains of seeds and plants, resulting in changes in the concentration of biochemical growing factors, a faster germination, and an initially more robust plant growth, even under stress conditions. These changes in phenotype are accompanied by differences in the concentration of biomarkers such as photosynthetic pigments (chlorophylls a and b and carotenoids), reactive oxygen species, and, particularly, the amino acid proline in the leaves of young plants, with changes that depend on environmental conditions and the application of a plasma treatment. This supports the idea that, rather than an increase in seed water imbibition capacity, there are clear beneficial effects on seedling of plasma treatments.


September, 2023 | DOI: 10.1021/acsagscitech.3c00121

Nanotecnología en Superficies y Plasma

Plasma assisted dry reforming of methane: Syngas and hydrocarbons formation mechanisms

Navascues, P; Cotrino, J; Gonzalez-Elipe, AR; Gomez-Ramirez, A
Fuel Processing Technology, 248 (2023) 107827

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Plasma reactions of CO2 + CH4 mixtures have been proposed as a suitable process for the dry reforming of methane. Without specific catalysts, most studies report the formation of CO and H2 as main reaction products and arise the question whether CHx radicals coming from CH4 may interact with intermediate species formed by electron impact dissociation of CO2, a critical step for the formation of high added value oxygenated compounds. We have addressed this question studying the CO2 + CH4 plasma reaction in a ferroelectric-moderated packed -bed reactor varying the reactants ratio. Analysis of the reaction products by mass spectrometry and the plasma reaction intermediates by optical emission spectroscopy suggest that few direct cross-link interactions exist between intermediate plasma species issued from CH4 or CO2. This preliminary evidence is corroborated by experiments using 13CO2 instead 12CO2 as reactant. The isotope labeling procedure has proved that plasma re-action mechanisms of CO2 and CH4 molecules proceed almost independently, with the formation of small amounts of water and the removal of carbon deposits resulting CH4 plasma decomposition as sole evidences of cross reactions. These results highlight the need of using catalysts to promote specific surface reactions for a better control of the selectivity of the process.


September, 2023 | DOI: 10.1016/j.fuproc.2023.107827

 

 

 

 

 

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